Applications of Metal-Organic-Frameworks in Electrodes of Lithium-Ion Batteries

Yongrui Zhang

2024

Abstract

Metal-organic frameworks (MOFs), with their unique structure and chemistry, are at the forefront of lithium-ion battery (LIB) technology development. This paper reviews recent advancements and applications of MOFs in LIB cathode and anode materials. As cathode materials, MOFs offer high specific surface areas and tunable pore sizes, ensuring fast lithium-ion diffusion and improved capacity retention after multiple charge-discharge cycles. Examples include nickel-based MOFs with an initial discharge capacity of 182 mAh/g and cobalt-based MOFs with stable capacities for over 200 cycles. Additionally, MOFs enhance the conductivity of traditional cathode materials like LiCoO2 significantly improving their electrochemical performance and thermal stability. On the anode side, MOFs improve cycling stability and capacity retention by addressing the volume expansion issues of high-capacity materials like silicon and hard carbon. Silicon-MOF composites have achieved preliminary capacities over 2100 mAh/g with good retention rates. MOF-modified graphite and hard carbon anodes also show improved initial coulombic efficiency and prolonged cycle life. Future developments will focus on simplifying and reducing the cost of MOF synthesis, addressing safety and environmental issues, and applying MOFs to new battery technologies. This collaboration aims to accelerate the commercialization and sustainable energy storage applications of MOF-based LIBs.

Paper Citation

in Harvard Style

Zhang Y. (2024). Applications of Metal-Organic-Frameworks in Electrodes of Lithium-Ion Batteries. In Proceedings of the 2nd International Conference on Renewable Energy and Ecosystem - Volume 1: ICREE; ISBN 978-989-758-776-4, SciTePress, pages 280-285. DOI: 10.5220/0013922200004914

in Bibtex Style

@conference{icree24,
author={Yongrui Zhang},
title={Applications of Metal-Organic-Frameworks in Electrodes of Lithium-Ion Batteries},
booktitle={Proceedings of the 2nd International Conference on Renewable Energy and Ecosystem - Volume 1: ICREE},
year={2024},
pages={280-285},
publisher={SciTePress},
organization={INSTICC},
doi={10.5220/0013922200004914},
isbn={978-989-758-776-4},
}

in EndNote Style

TY - CONF

JO - Proceedings of the 2nd International Conference on Renewable Energy and Ecosystem - Volume 1: ICREE
TI - Applications of Metal-Organic-Frameworks in Electrodes of Lithium-Ion Batteries
SN - 978-989-758-776-4
AU - Zhang Y.
PY - 2024
SP - 280
EP - 285
DO - 10.5220/0013922200004914
PB - SciTePress