The Use of Lithium-Ion Batteries as the Most Promising Traction
Current Sources
Lazizbek Daminov
1a
, Avaz Yangiboev
1b
, Rustamjon Mirzajonov
1c
and Yashnarbek Sharipov
2d
1
Tashkent State Technical University, 100095, University str. 2, Tashkent, Uzbekistan
2
Shakhrisabz Branch of the Tashkent Institute of Chemical Technology, 181306, Shahrisabz str. 20, Shahrisabz, Uzbekistan
Keywords: Lithium-Ion Batteries, Traction Current, Energy Efficiency.
Abstract: The article describes the advantages and disadvantages of using lithium-ion batteries as the most promising
traction current sources. The greatest number of cycles is typical for lithium titan ate batteries. This is
primarily due to the use of heavy metal as an anode material. This structure provides a long service life, high
charge-discharge currents, as well as a wide range of operating temperatures. The main disadvantage of this
type of battery is its low specific energy intensity compared to other materials. This is primarily due to the
low battery voltage level. The use of modified lithium nano-titanate makes it possible to increase the specific
energy intensity by 2 times, but this improvement significantly increases the cost of batteries.
1 INTRODUCTION
In most modern Li-Ion batteries, the negative
electrode is made of carbon materials. In such
batteries, not lithium metal or its alloys with other
metals are used as a negative electrode, but an
intercalation compound of carbon with lithium.
Carbon turned out to be a very convenient matrix for
intercalation (introduction) of lithium. The specific
volume of many carbons graphitized materials
changes by no more than 10% when a sufficiently
large amount of lithium is introduced. Carbon
electrodes containing not too much intercalated
lithium have a potential 0.5–0.8V higher than the
potential of the lithium electrode (Daminov et al.,
2022a). In order for the battery voltage to be high
enough, lithium cobalt oxides (lithium-cobalt),
manganese spinel, lithium iron phosphate, and so–
called multi-oxides (mixed oxides) were used as the
active material of the positive electrode. The potential
is approximately 4 V relative to the lithium electrode,
so that the operating voltage of the battery has a
characteristic value of 3.5−3.8 V. When the battery is
discharged, lithium is deintercalated from carbon
material (on the negative electrode) and lithium is
a
https://orcid.org/0000-0003-2179-9176
b
https://orcid.org/0000-0007-3750-0597
c
https://orcid.org/0000-0000-2838-9028
d
https://orcid.org/0000-0008-5289-8921
intercalated into oxide (on the positive electrode).
When charging, the processes go in the opposite
direction. Thus, there is no metallic lithium in the
entire system, and the discharge and charge processes
are reduced to the transfer of lithium ions from one
electrode to another. That is why the authors of such
a battery introduced the term lithium-ion battery.
At the same time, the name "rocking chair type
battery" (rocking chair cell) (Wei et al., 2024) or
"swing" batteries became stronger for this type of
batteries.
In the vast majority of lithium-ion batteries
brought to the stage of commercialization, the
negative electrode is made of carbon materials.
2 MATERIALS AND METHODS
The current-forming process on a negative electrode
is described by the equation 6C + xLi+ + xe-
LixC6. The forward process corresponds to the
charge, and the reverse process corresponds to the
discharge of the battery.
310
Daminov, L., Yangiboev, A., Mirzajonov, R. and Sharipov, Y.
The Use of Lithium-Ion Batteries as the Most Promising Traction Current Sources.
DOI: 10.5220/0014263400004738
Paper published under CC license (CC BY-NC-ND 4.0)
In Proceedings of the 4th International Conference on Research of Agricultural and Food Technologies (I-CRAFT 2024), pages 310-315
ISBN: 978-989-758-773-3; ISSN: 3051-7710
Proceedings Copyright © 2025 by SCITEPRESS Science and Technology Publications, Lda.
Figure 1: Schematic diagram of the operation of a lithium-
ion battery
A schematic diagram of the operation of a lithium-
ion battery is shown in Figure 1. On the left is a
negative graphite electrode. Its structure is
characterized by the presence of layers between
which lithium ions can be embedded (black dots). On
the right is a positive electrode made of lithium-
manganese spinel, in the structure of which lithium
ions can also be embedded. Solutions of lithium salts
in non-aqueous solvents are used as an electrolyte.
Lithium-ion batteries obey the laws common to all
types of batteries. An ideal battery should be
completely reversible: all electricity should be spent
only on current-generating charge and discharge
reactions (in other words, the current output of these
processes should be 100%). In a real battery, there are
always some processes (electrochemical and
chemical) in addition to current-forming reactions. A
certain amount of electricity is consumed for these
extraneous processes (usually irreversible). As a
result, at each cycle, the discharge capacity is less
than the amount of electricity consumed at the
previous stage of the charge. In addition, as cycling
goes on, the capacity decreases from cycle to cycle.
The nature of irreversible processes in batteries of
different electrochemical systems is different.
Processes on the positive electrode of a Li-ion
battery.
If a variety of active materials for the positive
electrode are used in primary lithium cells (meaning
non-rechargeable cells), then in lithium batteries the
choice of positive electrode material is limited.
Lithiated cobalt or nickel oxides, as well as lithium-
manganese spinels are used here. Currently, materials
based on mixed oxides or phosphates are increasingly
used as cathode materials. It is shown that the best
characteristics of the battery are achieved with
cathodes of mixed oxides. Technologies of cathode
surface coatings with finely dispersed oxides are also
being mastered. The problems of synthesis of these
compounds associated with the difference in the
structures of nickelate (layered hexagonal) and
lithium manganate (layered rhombohedral) were
overcome by using nickel and manganese double
hydroxide systems for synthesis, after which work
towards the synthesis of mixed oxides began to be
intensively carried out in different countries (USA,
CANADA, South Korea, China) (Matmurodov et al.,
2024, Wang et al., 2004, Shlyakhtin et al., 2004,
Kovtun et al., 2024, Musabekov et al., 2023).
High rated voltage, a gentle discharge curve, high
efficiency of the charging-discharge process, good
capacity and cyclability, acceptable self-discharge,
ease of production in industrial conditions explain the
most widespread use of lithium cobalt in
commercially developed LIAS, which provides a
reversible capacity of positive electrodes of 135-150
mAh/ g when cycling LIAS in the voltage range of
2.5-4.3 V. Smaller particle size, more uniform
distribution and the formation of small-sized
agglomerates of small spherical particles contribute
to improving the electrochemical characteristics of
the cathode material.
Modification of lithium metal–oxide
compounds by doping them, including multidoping
with various elements. The introduction of the latter
improves the stability of the electrochemical
characteristics of the cathode material during cycling
by stabilizing its structure and reducing the tendency
to phase transitions.
Table 1: The main manufacturers of cathode materials.
Chemical
formula of the
cathode
material
Country of
origin
Manufacturing
company
LiCoO2 Japan Nippon Chemical
industry Co.;
Simimoto Co.
USA OMG
German
y
Merck KGA
South Korea Umicore
China Shanghai
Shanshan Science
& Technolo
gy
Co.
LiNi1-
yCoyO2
Japan Simimoto Co.;
Seimi Chemical
Co
German
y
Merk KGA
LiMn2O4 Japan Mitsui Mining &
Smeltin
g
Co. Ltd
USA FMC Corp
German
y
Merk KGA
The Use of Lithium-Ion Batteries as the Most Promising Traction Current Sources
311
The search for other compounds with stable
structures led to the creation of a cathode material
with the formula LiNi0.33MN0.33Co0.33O2.The
discharge capacity of the resulting compound, which
has good cyclability, at a final voltage of 4.3-4.6 V
was 159-200 mAh /g, respectively. Doping of this
compound with silicon leads to an increase in the
parameters of the crystal lattice, which is
accompanied by an increase in specific capacitance,
speed capabilities and cyclability, as well as a
decrease in impedance.
3 RESULTS AND DISCUSSION
During operation (cycling and storage) LIA the most
significant changes occur on electrodes made of
lithium-manganese spinals.
During table cycling at room temperature, the
relatively unstable two-phase structure of LiMn2O4
turns into a stable single-phase one with the loss of
Mn3+ and the formation of MnO2, which transforms
during lithium intercalation into inactive LiMnO2
with a layered structure. When a positive electrode
based on lithium-manganese spinel is recharged to
potentials below 3.5 V, a distortion of the crystal
structure according to Jan-Teller (Bazarov et al.,
2024, Chen et al., 2024, Yehorov et al., 2024, Sessa
et al., 2018, Uddin et al., 2016) appears, leading to the
dissolution of spinel and slow degradation of the
capacity during cycling.
Negative electrodes. Carbon materials
In the initial period of development of lithium-ion
batteries, many carbon materials with the ability to
reversibly intercalate lithium were investigated. The
earliest studies concerned the intercalation of lithium
into graphite. Graphitized materials include natural
and synthetic graphite, highly oriented pyrolytic
graphite, modified graphite materials, including
MCMB (from the English "mesocarbon
microbeads"), carbon powders. Only some types of
carbon materials are widely used commercially,
which can be divided into two groups: materials with
a highly ordered crystal structure and with a
disordered structure (Casals et al., 2017, Kandasamy
et al., 2017, El Ghossein et al., 2019, Müller et al.,
2019, Zhang et al., 2018, Burzy´nski et al., 2019a,
Dudley et al., 2017).
Every six carbon atoms form graphene sheets,
similar to honeycombs. These graphene sheets under
the action of Vandervaals forces form graphite layers,
the latter, located parallel to each other, form a
graphite structure. From the point of view of
crystallography, the term "graphite" is applicable
only to carbon forms having a linear spatial structure
with an ideal ordered arrangement of graphene layers.
There are two types of graphite phases hexagonal
(α-phase) and rhombohedral (β-phase). The
rhombohedral phase is stable at lower temperatures
and therefore shows better stability during cycling.
To date, many different carbon materials have
been studied and the industry has mastered the
production of some special materials for the negative
electrodes of lithium-ion batteries. Examples of such
materials can be the MCMB material. However,
research on carbon materials for lithium-ion batteries
is still ongoing, with special attention being paid to
various nanofiber materials, nanotubes,
nanocomposites, graphene nanoparticles, etc. (Casals
et al., 2018, Jinlei et al., 2019, Lai et al., 2018, Zhang
et al., 2016).
Reversible processes on carbon materials
The maximum amount of lithium that can be
embedded in carbon is 1 lithium atom per 6 carbon
atoms (equation (1), 0<x<1). Lithium is embedded
through a prismatic surface. Insertion through the
basal surface is also possible, but only if there are
defects on this surface.
The mechanism of lithium intercalation into
graphite is the sequential filling of the space between
graphene layers with lithium. This process can be
described by a step index, which is equal to the
number of graphene layers between the two closest
lithium layers. At maximum filling, there will be only
one graphene layer between the lithium layers, and
this state will correspond to stage No. 1. Each stage is
characterized by a reversible potential and
corresponds to a certain concentration of lithium in
the graphite matrix. The transition through the steps
looks like this:
1. LiC72 + Li ↔ 2 LiC36
(Stage 8) (stage 4)
2. 3 LiC36 + Li ↔ 4 LiC27
(4 Stage) (3 Stage )
3. 2LiC27 + Li ↔ 3LiC18
(3 Stage) (2 Stage)
4. 2LiC18 + Li ↔ 3LiC12
(2 Stage) (2 Stage)
5. 2LiC12 + Li ↔ LiC6
(2 Stage) (1 Stage)
The mechanism of the introduction of lithium into
non-graphite carbon materials has not yet been fully
elucidated. But, at least, three types of interaction of
lithium and carbon material are assumed: interaction
with graphene layers, with the surface of polynuclear
aromatic planes and the introduction of lithium into
micro-voids on the frontal surface of the carbon
material. When lithium is intercalated into non-
I-CRAFT 2024 - 4th International Conference on Research of Agricultural and Food Technologies
312
graphite materials, lithium is filled simultaneously
throughout the entire volume of the carbon material,
so the charge-discharge curve has a smoothed
appearance, and there are no clear steps on the charge-
discharge curve (Nájera et al., 2017, Barcellona et al.,
2017, Umerov et al., 2024, DeHoog et al., 2018, Chin
et al., 2018, Daminov et al., 2022, DeSutter et al.,
2018, Fang et al., 2019, Xia et al., 2021).
Table 4 shows a list of operational indicators of
LIA with different chemical composition of the
cathode and anode.
Table 4: Comparative characteristics of electrochemical
systems used for the production of lithium-ion batteries
Type
(formula)
of
electroch
emical
system,
cathode/a
node
materials
Speci
fic
energy
intensity
(Wh/kg)
Reso
u
rce, (the
number
o
f charge
d
ischarg
e
cycles o
f
1C
d
ischarg
e
depth 80
%
Permis
sible
charge/disc
harge rates
in units
that are
multiples
of the
nominal
capacity
With –
(hourly
discharge
current)
Oper
ating
temperat
ure range
without
the use
of
passive
or active
thermal
compens
ation
systems
1 2 3 4 5
LiCoO2/
C
150-190 ≤ 200 0,5С/1С -15-
+50
LiMn2O
4/C
135 ≤1500 2С/5С -30-
+50
4 CONCLUSIONS
Lithium-ion batteries have emerged as the most
promising source of traction current for modern
electric vehicles (EVs), primarily due to their superior
energy density, long cycle life, and relatively low
self-discharge rates. These batteries represent a
significant advancement over traditional lead-acid
and nickel-metal hydride batteries, offering a more
efficient and sustainable solution to meet the growing
demands of electric mobility.
One of the key advantages of lithium-ion batteries
is their high energy density, which allows for longer
driving ranges on a single charge. This makes them
ideal for EVs, where maximizing range is crucial for
consumer acceptance and widespread adoption.
Additionally, lithium-ion batteries are known for their
longevity, maintaining their capacity over many
charge-discharge cycles, which translates to a longer
operational lifespan for EVs.
Moreover, lithium-ion technology is
characterized by a relatively low self-discharge rate,
meaning that the batteries retain their charge for
extended periods when not in use. This feature is
particularly beneficial for EV owners who may not
use their vehicles daily, as it ensures that the battery
will still have a substantial charge even after being
idle for some time (Noh et al., 2019, Somakettarin et
al., 2019, Burzy´nski et al., 2019b, Venugopal et al.,
2019, Worwood et al., 2018, Fan et al., 2019, Han et
al., 2019, Harting et al., 2019, Hildebrand et al., 2018,
Osara et al., 2019, Kuo et al., 2019, Wu et al., 2018,
Daminov et al., 2022).
Another significant benefit of lithium-ion
batteries is their efficiency in energy conversion,
which reduces the overall energy loss during charging
and discharging. This efficiency contributes to lower
energy costs and supports the economic viability of
EVs in the long term.
However, challenges such as safety concerns,
particularly regarding thermal runaway, and the
environmental impact of battery production and
disposal, must be addressed to fully realize the
potential of lithium-ion batteries. Ongoing research
and development are focused on improving battery
safety, enhancing recycling processes, and exploring
alternative materials that could further reduce
environmental impact.
In conclusion, lithium-ion batteries stand out as
the most promising traction current sources for
electric vehicles, offering a combination of high
energy density, long cycle life, and efficiency. With
continued innovation and improvements, these
batteries are poised to play a pivotal role in the future
of sustainable transportation.
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