
a vast range of surface coating materials all 
producing their own combustion spectra  
The following is a list of some of the more 
common surface coating materials.  
 
  Tungsten carbide/cobalt 
  Chromium carbide/nickel chromium 
  Aluminium bronze 
  Copper nickel indium 
  Hard alloys of iron 
 
To apply this technique of using 
monochromatic ultra violet lighting and narrow band 
pass filter to remove the combustion process, 
theoretical research into the spectrum produced by 
the specific process where autonomous control 
would be beneficial is required.  The reason for this 
is that the emission spectra of flames is sensitive to 
(Zirack): 
 
  temperature 
  gas/air or gas/oxygen mixture ratio 
  gas purity 
  burner type 
  gas flow (laminar or turbulent) 
  coating materials 
  height of observation in the flame 
 
Research can however provide reasonable 
indicators of a location for the band pass filter and 
where spectral problems may arise. The thermal 
spraying process used for this research was powder 
thermal spraying using an Oxy-Acetylene torch.  
4.2 Oxy-Acetylene Flame 
The Oxy-Acetylene flame is a chemical reaction 
resulting from the combination of acetylene C
2
H
2 
with oxygen 0
2
. Figure 13 shows the two stages of 
the chemical reactions (Materials Engineering 
Group, MEG) 
 
 
 
 
+ 
 
 
 
 
 
 
 
Figure 13: Oxy-Acetylene flame. 
A neutral flame with products of combustion 
CO
2
 and H
2
O is produced with maximum heat 
output when equal quantities of oxygen and 
acetylene are used (MEG). Controlling this mixture 
would form part of the overall thermal spraying 
robot control system.  
This is an idealised view and many other 
ordinary molecules and unstable radicals are 
produced in an Oxy-Acetylene flame in air. 
4.3  Oxy-Acetylene Emission Spectra  
The visible spectrum runs from 400 nm to 750 nm 
and the infra red spectrum runs from 750 nm to 1 
mm (HyperPhysics). This suggests a portion of the 
ultra violet spectrum between 350 – 400 nm 
commonly known as the UV-A spectrum for  the 
research as it excludes the visible and infra red 
spectrum.  
Research  is now concentrated on identifying 
weak spectra between 350 nm and 400 nm from the 
powder flame spraying Oxy-Acetylene in air flame 
with a range of molten surface coating materials, 
which is widely used in the powder spraying 
industry.  
The ordinary molecules which are the stable 
products of combustion, H
2
0
2
, C0
2
, C0, 0
2
 or N
2
 in 
hydrogen flames do not provide spectra of any 
appreciable strength in the visible or ultra violet 
spectrum (Zirack).  
The only product of combustion that may have 
an appreciable spectrum in the UV band is the 
hydroxyl radical OH which give band peaks at 281 
nm 306 nm and 343 nm. Oxyacetylene flames not 
only produce spectra of hydrogen flames but also 
emit radiation of hydrocarbon radicals. Between the 
350 nm and 400 nm wavelengths a weak CH band 
occurs at 387/9 nm and a strong band at 432 nm are 
found in air acetylene flames.  
This suggests many wavelengths between 350 
and 400 nm may be suitable for removing the Oxy-
Acetylene flame in air but we must add the spectrum 
from the surface coating material to ensure there is 
no appreciable interference from the molten material 
in our chosen UV band. This is an area for continued 
research. However a review of published work by 
De Saro relating to emission spectra of molten 
elements such as aluminium and copper provides 
information on spectra of interest as follows:  
Oxygen 0
2
Acetylene C
2
H
2
Stage 1  
C
2
H
2
  0
2
 = 2C0 +H
2
Stage 2  
C0 + H
2
 + 0
2
 = C0
2
 + H
2
0 
 
  Aluminium  390 – 400 nm 
  Iron   260 – 262 nm  
  Magnesium 380 - 385 nm 
  Copper    320 – 330 nm  
 
Results so far suggest using a narrow band pass 
filter and lighting between 350 and 370 nm 
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